Voltammetric Determination of Purine Bases Using a Carbon Electrode Modified With Hybrid Silica Film

被引:4
|
作者
Rozhanchuk, Tetiana [1 ]
Mariia, Velychko [1 ]
Titov, Maksim [1 ]
Tananaiko, Oksana [1 ]
机构
[1] Natl Taras Shevchenko Univ, Dept Analyt Chem, UA-01601 Kiev, Ukraine
关键词
Voltammetry; Sol-gel process; Purine base; Modified electrode; Silica film; SOL-GEL MATERIALS; ELECTROCHEMICAL OXIDATION; STRIPPING VOLTAMMETRY; ADENINE; DNA; GUANINE; RECOGNITION; COPPER; BEHAVIOR;
D O I
10.1002/elan.201300081
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Hybrid silica films containing cation-exchange polyelectrolytes were designed and used to modify a glassy carbon electrode (GCE) for voltammetric determination of purine bases. Hybrid silica-polyelectrolyte films synthesised in the presence of adenine as structure directed component have demonstrated enhanced sorption capacity to purine base. The anodic peaks of adenine and guanine at a hybrid film-modified GCE were observed at +1.55 and +1.1V, respectively, in phosphate buffer solution at pH3.5. Oxidation currents of adenine and guanine were proportional to their concentration in the range of 0.02-0.50mM, with a detection limit of 0.015mM. The developed method was used to determine adenine in adenosine triphosphate and purine bases in hydrolyzed solutions of DNA and demonstrated good metrological characteristics.
引用
收藏
页码:2045 / 2053
页数:9
相关论文
共 50 条
  • [1] Voltammetric determination of Chromium(VI) using a gold film modified carbon composite electrode
    Kachoosangi, Roohollah Torabi
    Compton, Richard G.
    SENSORS AND ACTUATORS B-CHEMICAL, 2013, 178 : 555 - 562
  • [2] VOLTAMMETRIC DETERMINATION OF PENTACHLOROPHENOL WITH A SILICA GEL-MODIFIED CARBON PASTE ELECTRODE
    BARRIO, MAR
    CARRAZON, JMP
    FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1992, 344 (1-2): : 34 - 38
  • [3] Voltammetric determination of bisphenol A using modified carbon paste electrode
    Jahani, Peyman Mohammadzadeh
    Beitollahi, Hadi
    Nejad, Fariba Garkani
    INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2024,
  • [4] Voltammetric Determination of Nitrite Using Modified Glassy Carbon Electrode
    Surface Engineering and Applied Electrochemistry, 2024, 60 : 15 - 23
  • [5] Voltammetric Determination of Nitrite Using Modified Glassy Carbon Electrode
    Beigmoradi, Fariba
    Beitollahi, Hadi
    SURFACE ENGINEERING AND APPLIED ELECTROCHEMISTRY, 2024, 60 (01) : 15 - 23
  • [6] Voltammetric Determination of Lead (II) and Cadmium (II) Using a Bismuth Film Electrode Modified with Mesoporous Silica Nanoparticles
    Yang, Die
    Wang, Liang
    Chen, Zuliang
    Megharaj, Mallavarapu
    Naidu, Ravi
    ELECTROCHIMICA ACTA, 2014, 132 : 223 - 229
  • [7] Electrochemical behavior and voltammetric determination of ammonium dinitramide using a graphene film modified glassy carbon electrode
    Najafi, Mostafa
    Darabi, Salman
    ELECTROCHIMICA ACTA, 2014, 121 : 315 - 320
  • [8] Voltammetric Determination of 3-Methylmorphine Using Glassy Carbon Electrode Modified with rGO and Bismuth Film
    Wong, Ademar
    Santos, Anderson M.
    Proenca, Camila A.
    Baldo, Thaisa A.
    Feitosa, Maria H. A.
    Moraes, Fernando C.
    Sotomayor, Maria D. P. T.
    BIOSENSORS-BASEL, 2022, 12 (10):
  • [9] Voltammetric determination of theophylline in pharmaceutical formulations using aligned carbon nanotubes (ACNTs) film modified electrode
    Wenbin Sun
    Jinlian Hu
    Journal of Analytical Chemistry, 2013, 68 : 694 - 699
  • [10] Voltammetric determination of theophylline in pharmaceutical formulations using aligned carbon nanotubes (ACNTs) film modified electrode
    Sun, Wenbin
    Hu, Jinlian
    JOURNAL OF ANALYTICAL CHEMISTRY, 2013, 68 (08) : 694 - 699