Single-step, highly active, and highly selective nanoparticle catalysts for the hydrogenation of key organic compounds

被引：1

作者：

Raja, R

Khimyak, T

Thomas, JM

Hermans, S

Johnson, BFG

机构：

[1] UCL Royal Inst Great Britain, Davy Faraday Res Lab, London W1S 3BS, England

[2] Dept Mat Sci & Met, Cambridge CB2 3QZ, England

[3] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 24期

关键词：

cluster compounds; heterogeneous catalysis; hydrogenation; platinum; ruthenium;

D O I：

10.1002/1521-3773(20011217)40:24<4638::AID-ANIE4638>3.0.CO;2-W

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pores for cluster catalysts: Nanoparticles of both Ru5Pt and Ru10Pt2, uniformly distributed along the inner walls of mesoporous silica, exhibit high catalytic performance in the single-step hydrogenation of dimethyl terephthalate (DMT, to 1,4-cyclohexanedimethanol (CHDM); see scheme), of benzoic acid (to cyclohexane carboxylic acid), and of naphthalene (in the presence of sulfur) to cisdecalin.

引用

页码：4638 / +

页数：6

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