A new general method for the generation of (alk-1-ynyl)halocarbenes by base solvolysis of 3-substituted 1,1,1,3-tetrahalopropanes

被引：0
|
作者：
Shavrin, KN
Gvozdev, VD
Nefedov, OM
机构：
[1] ND ZELINSKII INST ORGAN CHEM,MOSCOW 117913,RUSSIA
[2] RUSSIAN ACAD SCI,HIGHER CHEM COLL,MOSCOW 125820,RUSSIA
来源：
MENDELEEV COMMUNICATIONS | 1997年 / 04期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The (alk-1-ynyl)halocarbenes 4 have been generated from S-substituted 1,1,1,3-tetrahalopropanes 1 via elimination of three molecules of hydrogen halide by treatment with (BuOK)-O-t or with alkali metal hydroxides under phase-transfer catalysis conditions and have been trapped by alkenes to form 1-(alk-1-ynyl)-1-halocyclopropanes 5 in 40-70% yields.
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页码：144 / 145
页数：6
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