A Sandwich Zwitterionic Ruthenium Complex Bearing a Cyanamido Group

被引：4
|
作者：
Li, Junfei [1 ,2 ]
Kuai, Wenying [1 ,2 ]
Liu, Weiping [3 ]
Zheng, Wenjun [1 ,2 ]
机构：
[1] Shanxi Normal Univ, Inst Organ Chem, Linfen 041004, Shanxi Province, Peoples R China
[2] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi Province, Peoples R China
[3] Kunming Inst Precious Met, State Key Lab Platinum Grp Met, Kunming 650106, Yunnan Province, Peoples R China
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 15期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1021/om400547r
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A sandwich zwitterionic ruthenium complex (4) was prepared by an intramolecular 1,3-dipolar cydoaddition of the ruthenium azido isocyanide [CpMe5Ru(CNAr)(2)N-3] (2). The reaction involved a formal 1,3-migration mechanism along a highly conjugated system linking to a cyanamid group.
引用
收藏
页码：4050 / 4053
页数：4
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