Molecular structure in the solid state of bis(pentamethylcyclopentadienyl)germanium

被引：10

作者：

Schenk, C ^{[1
]}

Schnepf, A ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 09期

关键词：

D O I：

10.1021/om060051q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Decamethylgermanocene GeCp*(2) (1) (Cp* = Me5C5) was synthesized starting from a solution of GeBr and was obtained as colorless crystals. The molecular structure of 1 was determined by X-ray diffraction, showing that 1 is monomeric in the solid state, featuring two pentahapto-bonded Cp* ligands in a bent configuration with a bending angle of 162 degrees.

引用

页码：2378 / 2380

页数：3

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