The Ultrasmall Palladium Nanoparticles Catalyzed Telomerization of CO2with 1,3-Butadiene at Room Temperature: Selective Synthesis ofδ-Lactone

被引：10
|
作者：
Wang, Jixiao [1 ]
Feng, Xiujuan [1 ]
Song, Jiliang [1 ,2 ]
Gao, Zhanming [1 ]
Wang, Wan-Hui [1 ,2 ]
Bao, Ming [1 ,2 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China
[2] Dalian Univ Technol, Sch Chem Engn, Panjin 124221, Peoples R China
来源：
CHEMISTRYSELECT | 2020年 / 5卷 / 30期
基金：
中国国家自然科学基金;
关键词：
1; 3-Butadiene; C1 building blocks; Lactones; Palladium nanoparticles; Telomerization; CARBON-DIOXIDE; BUTADIENE; CO2; ACTIVATION; COMPLEXES; LIGANDS;
D O I：
10.1002/slct.202002203
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient method for the selective synthesis of delta-lactone from CO(2)and 1,3-butadiene was developed by using ultrasmall palladium nanoparticles as a catalyst for the first time. Palladium nanoparticles (1.90 +/- 0.39 nm) were generated in situ in the presence of Pd(acac)(2), tetrabutylammonium acetate (TBAAc), and PPh(3)as the precatalyst, stabilizer, and reductant, respectively. Maximum yield (86 % with 96 % selectivity) with satisfactory conversion (89 %) and turnover number (1271) was achieved under mild conditions.
引用
收藏
页码：9404 / 9408
页数：5
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