Ionic liquids assisted synthesis and luminescence properties of Ca5(PO4)3Cl:Ce3+,Tb3+ nanostructures

被引：13
|
作者：
Zou, Haoyang [1 ]
Song, Yanhua [1 ]
Deng, Yuefeng [2 ]
Zhang, Hongguang [1 ]
Sheng, Ye [1 ]
Zheng, Keyan [1 ]
Zhou, Xiuqing [1 ]
Chen, Ji [2 ]
机构：
[1] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
来源：
JOURNAL OF NANOPARTICLE RESEARCH | 2013年 / 15卷 / 10期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Ionic liquids; Calcium chloroapatite; Morphology controllable synthesis; Luminescence properties; HYDROTHERMAL SYNTHESIS; NANOPARTICLES; MECHANISM; NANORODS; POWDERS;
D O I：
10.1007/s11051-013-1973-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ca-5(PO4)(3)Cl straw-like sheaves and microrods were synthesized via a ionic liquids based hydrothermal method. The ionic liquids [Omim]Cl was utilized to introduce a new chloride source. The influences of the ionic liquids amount and reaction time on the final products were investigated in detail. A possible splitting formation mechanism for the interesting architectures has been proposed to interpret the growth process. The optical properties of the Ca-5(PO4)(3)Cl:Ce3+,Tb3+ phosphor with different morphology have been discussed. This ionic liquids based hydrothermal method is a novel and facile route for the synthesis of other apatite phosphors.
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页数：9
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