Stereoselective synthesis of macrolactin A analogues .2. The C-1-C-14 fragment

被引:20
|
作者
Benvegnu, TJ [1 ]
Gree, RL [1 ]
机构
[1] ECOLE NATL SUPER CHIM RENNES,CNRS URA 1467,LAB SYNTH & ACTIVAT BIOMOL,F-35700 RENNES,FRANCE
关键词
D O I
10.1016/0040-4020(96)00667-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A synthetic approach to the C-1-C-14 part of Macrolactin A analogues is presented. The sequence involving hydroboration-Pd degrees coupling reaction was found to be the most efficient in term of chemio- and stereo-selectivity to prepare the sensitive and functionalized E,Z diene unit. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:11821 / 11826
页数:6
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