Synthesis, effect of capping agents and optical properties of manganese-doped zinc sulphide nanoparticles

被引:19
|
作者
Murugadoss, G. [1 ]
Ramasamy, V. [1 ]
机构
[1] Annamalai Univ, Dept Phys, Annamalainagar 608002, Tamil Nadu, India
关键词
nanoparticles; PMMA; PEG; ZnSMn2+; quantum confinement; PHOTOPHYSICAL PROPERTIES; ZNS; NANOCRYSTALS; SURFACE; SEMICONDUCTORS; LUMINESCENCE; CRYSTALLITES; ADSORPTION; CHEMISTRY;
D O I
10.1002/bio.2346
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Mn2+-doped ZnS nanoparticles have been successfully synthesized by a chemical precipitation method, using non-ionic surfactants such as PMMA and PEG. The particles were prepared in an air atmosphere at 80 degrees C. X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-visible and photoluminescence (PL) studies were used to investigate the effect of the capping agent on the size, morphology and optical properties of the ZnSMn2+ nanoparticles. Enhanced PL was observed from the surfactant-capped ZnSMn2+ nanoparticles. The PL spectra showed a broad blue emission band in the range 460445nm and a Mn2+-related yellow-orange emission band in the range 581583nm. Copyright (c) 2012 John Wiley & Sons, Ltd.
引用
收藏
页码:69 / 75
页数:7
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