Palladium-Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates

被引：299
|
作者：
Ackermann, Lutz [1 ]
Althammer, Andreas [1 ]
Fenner, Sabine [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 01期
关键词：
C-H activation; direct arylation; heteroarenes; palladium; sulfonates; CROSS-COUPLING REACTIONS; H BOND ACTIVATION; C-H; ARYL CHLORIDES; HALOGENATED NITROGEN; FUNCTIONALIZATION; HETEROCYCLES; OXYGEN; 1,2,3-TRIAZOLES; PRELIGANDS;
D O I：
10.1002/anie.200804517
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) A toss up: A highly active palladium complex enabled the first direct arylation of heteroarenes through C-H bond functionalization using tosylates or mesylates as electrophiles with ample scope. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：201 / 204
页数：4
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