μ-Aqua-κ2O:O-di-μ-phenylacetato-κ4O:O′-bis[(1,10-phenanthroline-κ2N,N′)(phenylacetato-κO)cobalt(II)]

被引:7
|
作者
Kong, LL [1 ]
Huo, LH [1 ]
Gao, S [1 ]
Zhao, JG [1 ]
机构
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Lab Funct Mat, Harbin 150080, Peoples R China
关键词
D O I
10.1107/S1600536805035440
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title molecule, [Co-2(C8H7O2)(4)(C12H8N2)(2)(H2O)], is a dinuclear Co-II complex which is located on a twofold symmetry axis. Each Co-II ion is six-coordinated by three O atoms of different phenylacetate ligands, two N atoms of the 1,10-phenanthroline ligands and one O atom of a water molecule, giving a distorted octahedral geometry. The two Co-II atoms are bridged by two phenylacetate groups and the water molecule lying on the twofold axis. The (CoCo)-Co-... distance is 3.553 (2) angstrom. A one-dimensional supramolecular chain is constructed by pi - pi stacking interactions between adjacent 1,10- phenanthroline molecules.
引用
收藏
页码:M2485 / M2487
页数:3
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