Synthesis and photopolymerization of vinyl ether and epoxy-functionalized silicones

被引:7
|
作者
Pyun, SY
Kim, WG
机构
[1] Konkuk Univ, Dept Appl Chem, Chungju 380701, South Korea
[2] Pukyung Natl Univ, Dept Chem, Pusan 608737, South Korea
关键词
cationic polymerization; siloxane; silicone; uv-curing; vinyl ether; epoxy; hydrosilation;
D O I
10.1007/BF03218354
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
dThe reactive precursors, vinyl ethers, and epoxy-silicones, were synthesized. The vinyl ether monomers were prepared from primary alcohol and ethyl vinyl ether with mercury (II) acetate. The epoxy-functionalized silicones have been achieved by the controlled, rhodium-catalyzed, chemoselective hydrosilation of vinyl ether with siloxanes or silane. It was shown that the hydrosilation proceeds exclusively at the vinyl ether group of alkenyl vinyl ether without participation at the alkenyl group. The photoinduced cationic polymerization of these monomers was studied and found to be all highly reactive.
引用
收藏
页码:202 / 205
页数:4
相关论文
共 50 条
  • [1] Synthesis and photopolymerization of vinyl ether and epoxy-functionalized silicones
    Sang Yong Pyun
    Whan Gi Kim
    Macromolecular Research, 2003, 11 : 202 - 205
  • [2] Synthesis and photopolymerization of propenyl ether and epoxy functionalized siloxanes
    Kim, WG
    Ahn, HK
    Lee, HW
    Kim, SH
    Crivello, JV
    OPTICAL MATERIALS, 2003, 21 (1-3) : 343 - 347
  • [3] Non-aqueous sol–gel synthesis of epoxy-functionalized and epoxy and vinyl-functionalized poly(borosiloxane)s
    Deepa Devapal
    Viola B. Morris
    S. Suraj
    S. Packirisamy
    Journal of Sol-Gel Science and Technology, 2023, 107 : 133 - 148
  • [4] Non-aqueous sol-gel synthesis of epoxy-functionalized and epoxy and vinyl-functionalized poly(borosiloxane)s
    Devapal, Deepa
    Morris, Viola B.
    Suraj, S.
    Packirisamy, S.
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2023, 107 (01) : 133 - 148
  • [5] VINYL ETHER SILICONES
    HERZIG, C
    DAUTH, J
    DEUBZER, B
    WEIS, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 209 : 239 - PMSE
  • [6] Synthesis, characterization and photopolymerization of vinyl ether and acrylate functionalized hybrid oligo-caprolactone
    Liow, S. S.
    Lipik, V. T.
    Widjaja, L. K.
    Abadie, M. J. M.
    JOURNAL OF POLYMER RESEARCH, 2012, 19 (01)
  • [7] Synthesis, characterization and photopolymerization of vinyl ether and acrylate functionalized hybrid oligo-caprolactone
    S. S. Liow
    V. T. Lipik
    L. K. Widjaja
    M. J. M. Abadie
    Journal of Polymer Research, 2012, 19
  • [8] SELECTIVE VINYL CATIONIC POLYMERIZATION OF MONOMERS WITH 2 CATIONICALLY POLYMERIZABLE GROUPS .3. 2-VINYLOXYETHYL GLYCIDYL ETHER - AN EPOXY-FUNCTIONALIZED VINYL ETHER
    SAWAMOTO, M
    TAKEUCHI, E
    HASHIMOTO, T
    HIGASHIMURA, T
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1987, 25 (10) : 2717 - 2727
  • [9] Synthesis and characterization of the epoxy-functionalized quaternary ammonium chloride
    Liu, Yingwei
    Yang, Xiaodeng
    Li, Yan
    Chen, Yijian
    Zhou, Xiangzhu
    Li, Tianduo
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2016, 498 : 248 - 257
  • [10] Cationically photopolymerizable epoxy-functionalized thermoplastic polysilsesquioxanes: synthesis and properties
    Lee, A. S.
    Choi, S. S.
    Song, S. -J.
    Baek, K. -Y.
    Hwang, S. S.
    RSC ADVANCES, 2014, 4 (99) : 56532 - 56538