New synthetic routes to some nitrosyl rhenium complexes.: Crystal, molecular and electronic structure of [ReCl3(NO)(PPh3)2] and [ReCl2(CO)(NO)(PPh3)2] complexes

被引：18
|
作者：
Bartczak, TJ
Czurak, W
Dziegielewski, JO
Machura, B
Jankowska, A
Kusz, J
Warczewski, J
机构：
[1] Lodz Tech Univ, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland
[2] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland
[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland
来源：
POLYHEDRON | 1999年 / 18卷 / 17期
关键词：
rhenium; nitrosyl; x-ray structure; electronic structure; nitric oxide;
D O I：
10.1016/S0277-5387(99)00120-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of the nitrosyl rhenium(II) complex [ReCl3(NO)(OPPh3)(PPh3)] with triphenylphosphine, NaBH4 in the presence of PPh3, and CO in the presence of PPh3 were examined. The rhenium nitrosyl complexes [ReCl3(NO)(PPh3)(2)] (1), [ReCl2(CO)(NO)(PPh3)(2)] (2) and [ReH2(NO)(PPh3)(3)]. 1/2C(6)H(6) (3) obtained were characterised by IR, UV-Vis, NR IR (H-1 and P-31) and magnetochemical measurements. For 1 and 2, the electronic, crystal and molecular structures were determined. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2313 / 2320
页数：8
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