The 2,4,6-tris(trifluoromethyl) phenyl group: Methyl and vinyl ketones and related chemistry

被引：1
|
作者：
Filler, R
Kong, ZR
Zhang, ZX
Sinha, AK
Li, XF
机构：
[1] Dept. of Biol. Chem. and Phys. Sci., Illinois Institute of Technology, Chicago
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 80卷 / 02期
关键词：
aryl ketones; IR spectroscopy; mass spectrometry; NMR spectroscopy; reactions; 2,4,6-tris(trifluoromethyl)phenyl;
D O I：
10.1016/S0022-1139(96)03498-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
2,4,6-Tris(trifluoromethyl)phenyllithium (1) reacts with acetaldehyde and acrolein to give the corresponding alcohols 5 and 8. Oxidation of the alcohols with the CrO3-pyridine complex affords the acetophenone 3 and the vinyl ketone 7 respectively. The reactions of 1 with trifluoroacetic anhydride and trimethylsilyl trifluoroacetate give low to moderate yields of the trifluoroacetophenone 6.
引用
收藏
页码：71 / 75
页数：5
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