Solvent-free thiolysis of epoxides under lithium perchlorate catalysis

被引：6
|
作者：
Mojtahedi, Mohammad M. [1 ]
Abassi, Hassan [1 ]
Abaee, M. Saeed [1 ]
Mohebali, Bahareh [1 ]
机构：
[1] Chem & Chem Engn Res Ctr Iran, Tehran, Iran
来源：
MONATSHEFTE FUR CHEMIE | 2006年 / 137卷 / 04期
关键词：
thiols; epoxides; catalytic; lithium perchlorate; solvent-free;
D O I：
10.1007/s00706-005-0458-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solvent-free ring opening of 1,2-epoxides with thiols using catalytic amounts of lithium perchlorate affords high yields of beta-hydroxy sulfides. Nucleophilic attack of the thiols occurs regio-selectively at the sterically less hindered side of the epoxides.
引用
收藏
页码：455 / 458
页数：4
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