The physical and chemical properties of eumelanin

被引:816
|
作者
Meredith, Paul
Sarna, Tadeusz [1 ]
机构
[1] Univ Queensland, Sch Phys Sci, Soft Condensed Matter Phys Grp, Brisbane, Qld, Australia
[2] Jagiellonian Univ, Dept Biophys, Fac Biochem Biophys & Biotechnol, Krakow, Poland
来源
PIGMENT CELL RESEARCH | 2006年 / 19卷 / 06期
关键词
eumelanin; physical and chemical properties; structure-property relationships; pheomelanin; metal ion binding; electron exchange; redox state; free radicals; photodynamics; photoreactivity; photoprotection; antioxidant action; quantum chemical calculations; energy gap; electrical conductivity;
D O I
10.1111/j.1600-0749.2006.00345.x
中图分类号
Q2 [细胞生物学];
学科分类号
071009 ; 090102 ;
摘要
In this article, we review the current state of knowledge concerning the physical and chemical properties of the eumelanin pigment. We examine properties related to its photoprotective functionality, and draw the crucial link between fundamental molecular structure and observable macroscopic behaviour. Where necessary, we also briefly review certain aspects of the pheomelanin literature to draw relevant comparison. A full understanding of melanin function, and indeed its role in retarding or promoting the disease state, can only be obtained through a full mapping of key structure-property relationships in the main pigment types. We are engaged in such an endeavor for the case of eumelanin.
引用
收藏
页码:572 / 594
页数:23
相关论文
共 50 条
  • [1] Chemical and biophysical properties of eumelanin and pheomelanin
    Sarna, T.
    FEBS JOURNAL, 2009, 276 : 29 - 29
  • [2] Physical and Chemical Control of Interface Stability in Porous Si-Eumelanin Hybrids
    Antidormi, Aleandro
    Aprile, Giulia
    Cappellini, Giancarlo
    Cara, Eleonora
    Cardia, Roberto
    Colombo, Luciano
    Farris, Roberta
    d'Ischia, Marco
    Mehrabanian, Mehran
    Melis, Claudio
    Mula, Guido
    Pezzella, Alessandro
    Pinna, Elisa
    Riva, Eugenio Redolfi
    JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (49): : 28405 - 28415
  • [3] Eumelanin Graphene-Like Integration: The Impact on Physical Properties and Electrical Conductivity
    Di Capua, Roberto
    Gargiulo, Valentina
    Alfe, Michela
    De Luca, Gabriella Maria
    Skala, Tomas
    Mali, Gregor
    Pezzella, Alessandro
    FRONTIERS IN CHEMISTRY, 2019, 7
  • [4] Physical and chemical properties
    Anon
    Environmental Health Criteria, 1990, (113):
  • [5] Comparison of the structural and physical properties of human hair eumelanin following enzymatic or acid/base extraction
    Liu, Y
    Kempf, VR
    Nofsinger, JB
    Weinert, EE
    Rudnicki, M
    Wakamatsu, K
    Ito, S
    Simon, JD
    PIGMENT CELL RESEARCH, 2003, 16 (04): : 355 - 365
  • [6] Photovoltaic properties of PSi impregnated with eumelanin
    Mula, Guido
    Manca, Laura
    Setzu, Susanna
    Pezzella, Alessandro
    NANOSCALE RESEARCH LETTERS, 2012, 7
  • [7] Fluorescence properties of natural eumelanin biopolymer
    Perna, G.
    Palazzo, G.
    Mallardi, A.
    Capozzi, V.
    JOURNAL OF LUMINESCENCE, 2011, 131 (08) : 1584 - 1588
  • [8] Photovoltaic properties of PSi impregnated with eumelanin
    Guido Mula
    Laura Manca
    Susanna Setzu
    Alessandro Pezzella
    Nanoscale Research Letters, 7
  • [9] Physical and chemical properties of rhenium
    Acte, C
    Alterthum, H
    Becker, K
    Heyne, G
    Moers, K
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1931, 196 (02): : 129 - 159
  • [10] PHYSICAL AND CHEMICAL PROPERTIES OF OLIGOSACCHARIDES
    JOHNSON, JA
    SRISUTHEP, R
    CEREAL CHEMISTRY, 1975, 52 (01) : 70 - 78