The pore fluid of concretes is affected by radiolysis. Modelling this behavior for medium and long term must take into account the system heterogeneity, its complexity and its evolution capacity. From the basic scheme of alkaline water radiolysis (pH 13,25), influence of gaseous and liquid volumes, initial kinetics for H-2 production and O-2 consumption are discussed. in this context, the formation of a calcium peroxide seems to take a prominent part.
机构:CNRS, IMP, Inst Sci & Genie Mat & Procedes, BP 5, F-66125 Font Romeu, France
Paulmier, T
Balat-Pichelin, M
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CNRS, IMP, Inst Sci & Genie Mat & Procedes, BP 5, F-66125 Font Romeu, FranceCNRS, IMP, Inst Sci & Genie Mat & Procedes, BP 5, F-66125 Font Romeu, France
Balat-Pichelin, M
Le Quéau, D
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机构:CNRS, IMP, Inst Sci & Genie Mat & Procedes, BP 5, F-66125 Font Romeu, France
Le Quéau, D
Berjoan, R
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机构:CNRS, IMP, Inst Sci & Genie Mat & Procedes, BP 5, F-66125 Font Romeu, France
Berjoan, R
Robert, JF
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机构:CNRS, IMP, Inst Sci & Genie Mat & Procedes, BP 5, F-66125 Font Romeu, France
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Univ Marne la Vallee, FRE 2395 CNRS, Lab Phys Mat Div & Interfaces, F-77454 Champs sur Marne 2, FranceUniv Marne la Vallee, FRE 2395 CNRS, Lab Phys Mat Div & Interfaces, F-77454 Champs sur Marne 2, France