Synthesis and Crystal Structure of Two Coordination Polymers Assembled from a Versatile 4-(4-Hydroxypyridinium-1-yl)phthalic Acid

被引：8
|
作者：
Shan, Wen-Wen [1 ]
Ma, Shan-Shan [1 ]
Wang, Hong-li [1 ]
Li, Hai-Hua [1 ]
Meng, Rui-Jing [1 ]
Mei, Chong-Zhen [1 ]
机构：
[1] North China Univ Water Resources & Elect Power, Zhengzhou 450011, Peoples R China
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2014年 / 24卷 / 02期
关键词：
4-(4-Hydroxypyridinium-1-yl)phthalic acid; Ni(II) and Mn(II) coordination polymers; UV-vis absorption spectra; ZEOLITIC IMIDAZOLATE FRAMEWORKS; METAL-ORGANIC FRAMEWORK; MOLECULES; NETWORKS; CD(II); CD; CO;
D O I：
10.1007/s10904-013-0002-z
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two coordination polymers, namely, [Ni(L)(C2H3N)(H2O)(5)] (n) (1), and [Mn(L)(H2O)(2)] (n) (2) have been hydro(solvo)thermally synthesized through the reaction of 4-(4-hydroxypyridinium-1-yl)phthalic acid (H2L) with divalent nickel and manganese salts. As a result of various coordination modes of the versatile 4-(4-hydroxypyridinium-1-yl)phthalic acid, these compounds exhibit structural diversity. Complex 1 exhibits a 3D coordination framework through the rich hydrogen bond. Complex 2 exhibits a 3D coordination network based on layers. These complexes have been characterized by powder X-ray diffractions (PXRD), IR spectroscopy, elemental analysis, thermogravimetry, single-crystal X-ray crystallography and solid UV spectroscopy.
引用
收藏
页码：468 / 475
页数：8
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