Syntheses and characterizations of two new organic-inorganic hybrids based on heteropolymolybdates and piperidine molecules

被引：0
|
作者：
Zhou, DW
Zhang, H [1 ]
Yang, ZF
机构：
[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
[2] Jilin Inst Chem Technol, Dept Pharm & Appl Chem, Jilin 132073, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 25卷 / 03期
关键词：
organic-inorganic hybrids; heteropolymolybdates; piperidine molecules;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new organic-inorganic compounds [(CH2)(5)NH2](3)[PMO12O40]center dot 3[(CH2)(5)NH] 1 and [(CH2)(5)NH2](6)[P2MO18O62]center dot 5H(2)O 2 have been synthesized using conventional and hydrothermal methods, respectively, and characterized by elemental analyses, IR, TG and single-crystal X-ray diffraction. X-ray analyses show that in these compounds heteropolymolybdates [PMo12O40](3-) and [P2Mo18O62](6-) are reserved their Keggin or Dawson structures and linked to piperidine through. electrostatic and hydrogen-bonding interactions.
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页码：312 / 320
页数：9
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