Fluorinated Alcohols as Activators for the Solvent-Free Chemical Fixation of Carbon Dioxide into Epoxides

被引：103
|
作者：
Gennen, Sandro [1 ]
Alves, Margot [2 ]
Mereau, Raphael [2 ]
Tassaing, Thierry [2 ]
Gilbert, Bernard [3 ]
Detrembleur, Christophe [1 ]
Jerome, Christine [1 ]
Grignard, Bruno [1 ]
机构：
[1] Univ Liege, CERM, Dept Chem, B-4000 Liege, Belgium
[2] Univ Bordeaux, ISM, CNRS UMR5255, F-33405 Talence, France
[3] Univ Liege, Dept Chem, B-4000 Liege, Belgium
来源：
CHEMSUSCHEM | 2015年 / 8卷 / 11期
关键词：
carbon dioxide; carbonates; epoxides; fluor; organocatalysis; CYCLIC CARBONATES; HYDROGEN-PEROXIDE; IONIC LIQUIDS; EFFICIENT SYNTHESIS; CO2; CATALYSTS; ORGANOCATALYSTS; EPOXIDATION; AMMONIUM; IODIDES;
D O I：
10.1002/cssc.201500103
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The addition of fluorinated alcohols to onium salts provides highly efficient organocatalysts for the chemical fixation of CO2 into epoxides under mild experimental conditions. The combination of online kinetic studies, NMR titrations and DFT calculations allows understanding this synergistic effect that provides an active organocatalyst for CO2/epoxides coupling.
引用
收藏
页码：1845 / 1849
页数：5
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