Synthesis of strained bi- and tricyclic systems by rearrangements of some bromosubstituted camphor derivatives

被引：2
|
作者：
Komarov, IV [1 ]
Kornilov, MY [1 ]
Gorichko, MV [1 ]
机构：
[1] Kiev Taras Shevchenko Univ, Dept Chem, UA-252033 Kiev, Ukraine
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 20期
关键词：
D O I：
10.1016/S0040-4039(99)00613-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Bromosubstituted camphor derivatives can be conveniently used to create some sterically congested bi- and tricyclic compounds by rearrangement reactions with nucleophilic reagents. The ease of these thermo-dynamically unfavorable reactions is explained by alignment of the migrating and breaking bonds within the rigid framework of camphor-derived skeleton. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3935 / 3936
页数：2
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