Rhodium(III)-Catalyzed C-H Activation and Amidation of Arenes Using N-Arenesulfonated Imides as Amidating Reagents

被引：115
|
作者：
Yu, Songjie [1 ]
Wan, Boshun [1 ]
Li, Xingwei [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 14期
关键词：
CATALYZED DIRECT AMINATION; BOND FORMATION; ALKENES; CHLOROAMINES; ISOCYANATES; REACTIVITY; VERSATILE; MECHANISM; ELECTRON; ALKYNES;
D O I：
10.1021/ol401569u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rhodium(III)-catalyzed C-H-activation amidation of arenes bearing chelating groups has been achieved using N-arenesulfonated imides as efficient amidating reagents without using any base additive. Pyridine, oxime, and pyrimidine proved to be viable directing groups.
引用
收藏
页码：3706 / 3709
页数：4
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