Density, viscosity, refractive index, and speed of sound in binary mixtures of 2-chloroethanol with methyl acetate, ethyl acetate, n-propyl acetate, and n-butyl acetate

被引:91
|
作者
Aralaguppi, MI [1 ]
Jadar, CV [1 ]
Aminabhavi, TM [1 ]
机构
[1] Karnatak Univ, Dept Chem, Dharwad 580003, Karnataka, India
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D O I
10.1021/je980218p
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental values of density, viscosity, and refractive index at 298.15, 303.15, and 308.15 K and the speed of sound at 298.15 K in the binary mixtures of 2-chloroethanol with methyl acetate, ethyl acetate, propyl acetate, and butyl acetate are presented over the whole range of mixture composition. From these data, excess molar volume, deviations in viscosity, speed of sound, isentropic compressibility, and Lorenz-Lorentz molar refraction have been calculated. These results are fit to a Redlich-Kister type polynomial equation of the third degree to derive the binary coefficients. The values of standard deviations are estimated for the calculated and experimental data.
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页码:441 / 445
页数:5
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