Cytochrome P-450 model compound catalyzed selective hydroxylation of C-H bonds: Dramatic solvent effect

被引：24

作者：

Agarwala, Arunava ^{[1
]}

Bandyopadhyay, Debkumar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, New Delhi 110016, India

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 46期

关键词：

D O I：

10.1039/b611988c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective hydroxylation of cyclohexane and cyclohexene by t-BuOOH in presence of F20TPPFe(III) Cl as the catalyst has been achieved at room temparature in high yields.

引用

页码：4823 / 4825

页数：3

共 50 条

[1] Selective hydroxylation of a steroid at C-9 by an artificial cytochrome P-450
2000, Wiley-VCH Verlag (39):
[2] Selective hydroxylation of a steroid at C-9 by an artificial cytochrome P-450
Yang, J
Breslow, R
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2000, 39 (15) : 2692 - 2694
[3] Nonsynchronous concerted mechanism for cytochrome P-450 catalyzed hydroxylation
Newcomb, Martin
Tadic-Biadatti, Marie Helene Le
Chestney, Daryl L.
Roberts, Elizabeth S.
Hollenberg, Paul F.
Journal of the American Chemical Society, 1995, 117 (49):
[4] A predictive pattern of computed barriers for C-H hydroxylation by compound I of cytochrome P450
de Visser, SP
Kumar, D
Cohen, S
Shacham, R
Shaik, S
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (27) : 8362 - 8363
[5] Selective aerobic hydroxylation of C-H bonds with light-driven P450 biocatalysts
Cheruzel, Lionel E.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[6] Biocatalytic hydroxylation tertiary C-H bonds for synthesis of chiral tertiary alcohols by cytochrome P450
Zhang, Ru-Yue
Ma, Ting
Liu, Dan
Yang, Yu-Li
Gao, Luo
Cui, Hai-Bo
Wang, Zhong-Qiang
Chen, Yong-Zheng
MOLECULAR CATALYSIS, 2024, 553
[7] Selective catalytic hydroxylation of a steroid by an artificial cytochrome P-450 enzyme
Breslow, R
Zhang, XJ
Huang, Y
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (19) : 4535 - 4536
[8] Model compound studies related to cytochrome P-450
Nam, WW
JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 74 (1-4) : 42 - 42
[9] EFFECT OF SUPEROXIDE GENERATION AND DISMUTATION ON HYDROXYLATION REACTIONS CATALYZED BY LIVER MICROSOMAL CYTOCHROME P-450
STROBEL, HW
COON, MJ
JOURNAL OF BIOLOGICAL CHEMISTRY, 1971, 246 (24) : 7826 - &
[10] Selective Hydroxylation of Alkanes Catalyzed by Cytochrome P450 Enzymes
Wang, Xiling
Chen, Jie
Ma, Nana
Cong, Zhiqi
ACTA CHIMICA SINICA, 2020, 78 (06) : 490 - 503

← 1 2 3 4 5 →