Thermophysical Properties of High Temperature Reacting Mixtures of Carbon and Water in the Range 400-30,000 K and 0.1-10 atm. Part 2: Transport Coefficients

被引:25
|
作者
Wang, WeiZong [1 ,2 ]
Yan, J. D. [1 ]
Rong, MingZhe [2 ]
Murphy, A. B. [3 ]
Spencer, J. W. [1 ]
机构
[1] Univ Liverpool, Dept Elect Engn & Elect, Liverpool L69 3GJ, Merseyside, England
[2] Xi An Jiao Tong Univ, State Key Lab Elect Insulat & Power Equipment, Xian 710049, Shaanxi, Peoples R China
[3] CSIRO Mat Sci & Engn, Lindfield, NSW 2070, Australia
关键词
Carbon; Water; Thermal plasmas; Chapman-Enskog method; Transport properties; Viscosity; Thermal conductivity; Electrical conductivity; Diffusion coefficient; ENERGY-ELECTRON SCATTERING; TOTAL CROSS-SECTIONS; ELASTIC-SCATTERING; CHARGE-TRANSFER; MOLECULE SCATTERING; COLLISION INTEGRALS; OXYGEN; MODEL; ARGON; POLARIZABILITY;
D O I
10.1007/s11090-012-9365-0
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The present contribution is continuation of Part 1: Equilibrium composition and thermodynamic properties. This paper is devoted to the calculation of transport properties of mixtures of water and carbon at high temperature. The transport properties, including electron diffusion coefficient, viscosity, thermal conductivity, and electrical conductivity are obtained by using the Chapman-Enskog method expanded to the third-order approximation (second-order for viscosity), taking only elastic processes into account. The calculations, which assume local thermodynamic equilibrium, are performed for atmospheric pressure plasmas in the temperature range from 400 to 30,000 K for pressures of 0. 10, 1.0, 3.0, 5.0 and 10.0 atm. with the results obtained are compared to those of previously published studies, and the reasons for discrepancies are analyzed. The results provide reliable reference data for simulation of plasmas in mixtures of carbon and water.
引用
收藏
页码:495 / 518
页数:24
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