Synthesis of model molecules and NMR analysis of polymeric reagents based on propane-1,3-dithiol and 1,3-dithiane systems

被引：0
|
作者：
Lucchesini, F
Bertini, V
Pocci, M
Micali, E
De Munno, A
机构：
[1] Univ Genoa, Dipartimento Chim & Tecnol Farmaceut & Alimentari, I-16147 Genoa, Italy
[2] Univ Pisa, Dipartimento Chim & Chim Ind, I-56100 Pisa, Italy
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 2002卷 / 09期
关键词：
NMR spectroscopy; solid-phase synthesis; polymers; sulfur heterocycles;
D O I：
10.1002/1099-0690(200205)2002:9<1546::AID-EJOC1546>3.0.CO;2-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Purposely synthesized model compounds, one- and two-dimensional NMR spectra and simulations are used for a full H-1 and C-13 NMR spectroscopic investigation of soluble copolymeric reagents for supported organic syntheses containing (1,3-propanediyl)bis(benzenesulfonate), (1,3-propanediyl)bis(thioacetate), propane-1,3-dithiol, and 1,3-dithiane functions, The collected NMR spectroscopic data confirm the possibility of rapid and accurate assessments of preparations and applications of the newly prepared copolymeric reagents, without resorting to special equipment.
引用
收藏
页码：1546 / 1550
页数：5
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