Synthesis, Structures, and Photoluminescent Properties of Cyclometalated Platinum(II) Complexes bearing Upper-Rim Phosphinated Calix[4]arenes

被引：20
|
作者：
Lai, Siu-Wai [1 ]
Chan, Queenie K. -W.
Han, Jie
Zhi, Yong-Gang
Zhu, Nianyong
Che, Chi-Ming
机构：
[1] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Dept Chem, HKU CAS Joint Lab New Mat, Hong Kong, Hong Kong, Peoples R China
来源：
ORGANOMETALLICS | 2009年 / 28卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ANION RECOGNITION PROPERTIES; RECEPTOR MOLECULES; LUMINESCENT; RUTHENIUM(II); LIGANDS; BIPYRIDYL; BINDING; CAVITY; FUNCTIONALIZATION; COBALTOCENIUM;
D O I：
10.1021/om800969z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of upper-rim diphosphinated calixarene receptors bearing various R and R' substituents at the lower riin (L-n; n = 1-5) were synthesized, and their reactions with [Pt(Thpy)(HThpy)Cl] afforded the phosphorescent platinum(II)modified calixarene receptors [(PtThpyCl)(2)L-n]. The structure of [[PtThpy(CH3CN)](2)L-1](ClO4)(2) and [(PtThpvCl)(2)L-5] were determined by X-ray crystallographic analysis, and the photophysical properties of [(PtThpyCl)(2)L-n] were investigated.
引用
收藏
页码：34 / 37
页数：4
相关论文
共 50 条
  • [1] Selective Upper-Rim Adamantylation of Calix[4]arenes
    E. A. Shokova
    A. N. Khomich
    V. V. Kovalev
    Russian Journal of Organic Chemistry, 2001, 37 : 612 - 619
  • [2] SYNTHESIS OF CALIX[4]ARENES CARRYING BULKY UPPER-RIM GROUPS
    SHARMA, SK
    GUTSCHE, CD
    TETRAHEDRON LETTERS, 1993, 34 (34) : 5389 - 5392
  • [3] Selective upper-rim adamantylation of calix[4]arenes
    Shokova, EA
    Khomich, AN
    Kovalev, VV
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2001, 37 (05) : 612 - 619
  • [4] Synthesis and Properties of Upper Rim Schiff Base Calix[4]arenes
    Tie-Dong Guo
    Qi-Yu Zheng
    Lian-Ming Yang
    Zhi-Tang Huang
    Journal of inclusion phenomena and macrocyclic chemistry, 2000, 36 : 327 - 333
  • [5] Synthesis and properties of upper rim Schiff base calix[4]arenes
    Guo, TD
    Zheng, QY
    Yang, LM
    Huang, ZT
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2000, 36 (03) : 327 - 333
  • [6] Upper-rim functionalised calix[4]arenes for chemoselective Au3+ detection
    Bew, Sean P.
    Sharma, Sunil V.
    Gardiner, William H.
    ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (10): : 2397 - 2404
  • [7] Upper-rim monofunctionalization of calix[4]arene by organometallic diphenylphosphinorhodium complexes
    Vézina, M
    Gagnon, J
    Villeneuve, K
    Drouin, M
    Harvey, PD
    CHEMICAL COMMUNICATIONS, 2000, (12) : 1073 - 1074
  • [8] Synthesis of chiral calix[4]arenes bearing long alkyl groups at upper rim
    Zhou, Jin-Lan
    Chen, Xian-Jie
    Zheng, Yan-Song
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2008, 28 (07) : 1209 - 1212
  • [9] Coordination and organometallic polymers and oligomers of upper-rim functionalized calix[4]arenes by transition metals
    Harvey, PD
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2004, 14 (04) : 211 - 226
  • [10] Photoswitchable calix[4]arenes bearing dihydroacridine substituents at the upper rim
    Grubert, Lutz
    Abraham, Wemer
    TETRAHEDRON, 2007, 63 (44) : 10778 - 10787
12345