Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity

被引：775
|
作者：
Budd, PM
Elabas, ES
Ghanem, BS
Makhseed, S
McKeown, NB
Msayib, KJ
Tattershall, CE
Wang, D
机构：
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[2] Univ Wales Coll Cardiff, Sch Chem, Cardiff CF10 3TB, S Glam, Wales
来源：
ADVANCED MATERIALS | 2004年 / 16卷 / 05期
关键词：
D O I：
10.1002/adma.200306053
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A polymer with a rigid, randomly contorted molecular structure (see Figure), incorporating fused rings connected by spiro-centres, may be precipitated or cast from solution to give microporous powders and membranes stable up to temperatures of 350degreesC, with apparent surface areas > 600 m(2) g(-1). Organophilic membranes may be formed, as demonstrated by the separation of phenol from water by pervaporation.
引用
收藏
页码：456 / +
页数：5
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