Quantitative study of the formation of inorganic chemical species following corona discharge .1. Production of HNO2 and HNO3 in a composition-controlled, humid atmosphere

被引:20
|
作者
Pinart, J
Smirdec, M
Pinart, ME
Aaron, JJ
Benmansour, Z
Goldman, M
Goldman, A
机构
[1] UNIV PARIS 07,INST TOPOL & DYNAM SYST,CNRS,URA 34,F-75005 PARIS,FRANCE
[2] ECOLE SUPER ELECT,CNRS,PHYS DECHARGES LAB,F-91192 GIF SUR YVETTE,FRANCE
关键词
corona discharge; nitrites; nitrates; radical mechanism;
D O I
10.1016/1352-2310(95)00231-M
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Nitrous and nitric acid formed after exposure to a corona discharge in a composition-controlled humid atmosphere were collected in an aqueous liquid phase at room temperature. It was found that the production of NO2- and NO3- ions at the trace level increased linearly with the corona discharge time, electric current intensity and quantity of electricity. The relative amount of nitrates formed was larger than that of nitrites.
引用
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页码:129 / 132
页数:4
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