P2O5/SiO2 as an Efficient and Mild Catalyst for Trimethylsilylation of Alcohols Using Hexamethyldisilazane

被引：1

作者：

Eshghi, Hossein ^{[1
]}

Rahimizadeh, Mohammad ^{[1
]}

Ghadamyari, Zohreh ^{[1
]}

Shiri, Ali ^{[1
]}

机构：

[1] Ferdowsi Univ Mashhad, Fac Sci, Dept Chem, Mashhad 917751436, Iran

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 10期

关键词：

HMDS; hydroxyl group; protection; trimethylsilylation; ONE-POT SYNTHESIS; ALPHA-HYDROXYPHOSPHONATES; RECYCLABLE CATALYST; SELECTIVE OXIDATION; HYDROXYL-GROUPS; SILYLATION; PROTECTION; PHENOLS; HMDS; TRIMETHYLSILYLOXYPHOSPHONATES;

D O I：

10.1080/15533174.2012.682686

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The protection of alcohols with hexamethyldisilazane (HMDS) in the presence of P2O5/SiO2 at very mild and ambient condition with short reaction times is accomplished in excellent yields. P2O5/SiO2 catalyst is an efficient solid acid and heterogeneous catalyst for this transformation and easily recovered and reused for several times without significant decrease in its activity. Selectivity studies showed competitive reaction of primary alcohols over secondary alcohols and phenols.

引用

页码：1435 / 1439

页数：5

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