Facile synthesis of heterotrimetallic metal-string complex [NiCoRh(dpa)4Cl2] through direct metal replacement

被引：32
|
作者：
Cheng, Ming-Chuan [1 ,2 ]
Mai, Chi-Lun [3 ]
Yeh, Chen-Yu [3 ]
Lee, Gene-Hsiang [1 ]
Peng, Shie-Ming [1 ,2 ]
机构：
[1] Natl Taipei Univ Technol, Dept Chem, Taipei 106, Taiwan
[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan
[3] Natl Chung Hsing Univ, Dept Chem, Taichung 40227, Taiwan
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 72期
关键词：
LOW-SYMMETRY DISTORTIONS; ATOM CHAINS; ELECTRON-TRANSPORT; LIGANDS; CONDUCTANCE; BONDS;
D O I：
10.1039/c3cc43909g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This communication provides a practical strategy for the synthesis of heterotrimetallic extended metal atom chains with supported dpa(-) ligands. The transformation of the CoCoRh to a NiCoRh trinuclear complex can be achieved by direct metallic replacement. Furthermore, the first (CoRh)(4+) metal-metal bond is described here.
引用
收藏
页码：7938 / 7940
页数：3
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