Formic Acid as a Hydrogen Source for the Additive-Free Reduction of Aromatic Carbonyl and Nitrile Compounds at Reusable Supported Pd Catalysts

被引:8
|
作者
Tomar, Pooja [1 ,2 ]
Nozoe, Yuou [1 ]
Ozawa, Naoto [1 ]
Nishimura, Shun [1 ,3 ]
Ebitani, Kohki [1 ,3 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, 1-1 Asahidai, Nomi, Ishikawa 9231292, Japan
[2] Univ Delhi, M Tech CSPT, Dept Chem, Delhi 110007, India
[3] Japan Adv Inst Sci & Technol, Grad Sch Adv Sci & Technol, 1-1 Asahidai, Nomi, Ishikawa 9231292, Japan
关键词
formic acid; reduction; carbonyls; nitriles; Pd catalyst; GAMMA-VALEROLACTONE; CONVERSION; NANOPARTICLES; EFFICIENT; BIOMASS; DECOMPOSITION; NITROARENES; OXIDATION; WATER; DEHYDROGENATION;
D O I
10.3390/catal10080875
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Formic acid can be used as a hydrogen source for the hydrogenations of various aromatic carbonyl and nitrile compounds into their corresponding alcohols and amines using reusable heterogeneous Pd/carbon and Pd/Al(2)O(3)catalysts, respectively, under additive-free and mild reaction conditions.
引用
收藏
页码:1 / 10
页数:10
相关论文
共 50 条
  • [1] Highly Efficient Hierarchical Porous Carbon Supported Pd-Based Catalysts for Additive-Free Dehydrogenation of Formic Acid
    Miao, Xinyi
    Tian, Fengwu
    Bai, Miaomiao
    Zhang, Yujia
    Wang, Wei
    Zhao, Zuoping
    Shao, Xianzhao
    Ji, Xiaohui
    CATALYSTS, 2022, 12 (02)
  • [2] Hydrogen Evolution from Additive-Free Formic Acid Dehydrogenation Using Weakly Basic Resin-Supported Pd Catalyst
    Li, Lichun
    Chen, Xiangcan
    Zhang, Cheng
    Zhang, Geshan
    Liu, Zongjian
    ACS OMEGA, 2022, 7 (17): : 14944 - 14951
  • [3] Pd nanoparticles supported on CeO2 nanospheres as efficient catalysts for dehydrogenation from additive-free formic acid at low temperature
    Gao, Yibo
    Hu, Erjiang
    Yin, Geyuan
    Huang, Zuohua
    FUEL, 2021, 302
  • [4] Investigation of the Catalytic Performance of Pd/CNFs for Hydrogen Evolution from Additive-Free Formic Acid Decomposition
    Sanchez, Felipe
    Motta, Davide
    Bocelli, Ludovica
    Albonetti, Stefania
    Roldan, Alberto
    Hammond, Ceri
    Villa, Alberto
    Dimitratos, Nikolaos
    C-JOURNAL OF CARBON RESEARCH, 2018, 4 (02):
  • [5] Degradation of trichloroethylene by hydrodechlorination using formic acid as hydrogen source over supported Pd catalysts
    Yu, Xin
    Wu, Ting
    Yang, Xue-Jing
    Xu, Jing
    Auzam, Jordan
    Semiat, Raphael
    Han, Yi-Fan
    JOURNAL OF HAZARDOUS MATERIALS, 2016, 305 : 178 - 189
  • [6] Transfer hydrogenation of phenol on supported Pd catalysts using formic acid as an alternative hydrogen source
    Zhang, Damin
    Ye, Feiyang
    Xue, Teng
    Guan, Yejun
    Wang, Yi Meng
    CATALYSIS TODAY, 2014, 234 : 133 - 138
  • [7] Effect of the amine group content on catalytic activity and stability of mesoporous silica supported Pd catalysts for additive-free formic acid dehydrogenation at room temperature
    Jin, Min-Ho
    Park, Ju-Hyoung
    Oh, Duckkyu
    Park, Jong-Soo
    Lee, Kwan-Young
    Lee, Dong-Wook
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (10) : 4737 - 4744
  • [8] Structure-sensitivity of formic acid dehydrogenation reaction over additive-free Pd NPs supported on activated carbon
    Santos, Jose Luis
    Megias-Sayago, Cristina
    Ivanova, Svetlana
    Centeno, Miguel Angel
    Odriozola, Jose Antonio
    CHEMICAL ENGINEERING JOURNAL, 2021, 420
  • [9] Additive-Free Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst
    Curley, Julia B.
    Bernskoetter, Wesley H.
    Hazari, Nilay
    CHEMCATCHEM, 2020, 12 (07) : 1934 - 1938
  • [10] Hydrogen production from additive-free formic acid over highly active metal organic frameworks-supported palladium-based catalysts
    Ma, Caijun
    Duan, Jiachao
    Fu, Yan
    Chang, Jie
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (07) : 5259 - 5269