The first structurally characterized example of a η5-coordinate mesitylato palladium complex

被引：7
|
作者：
Klein, A [1 ]
Dogan, A [1 ]
机构：
[1] Univ Stuttgart, Inst Anorgan Chem, D-70550 Stuttgart, Germany
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 11期
关键词：
D O I：
10.1021/om010922q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The red complex [(COD)Pd(OMes)](SbF6)(OMes = 2,4,6-trimethylphenolate = mesitylate) was prepared and structurally characterized. The molecular structure reveals that the palladium atom coordinates eta(5) to the aryl pi system and not to the negatively charged oxygen atom on the mesitylate ligand.
引用
收藏
页码：2340 / 2342
页数：3
相关论文
共 50 条
  • [1] A 5-COORDINATE MONONUCLEAR COPPER COMPLEX
    HANSON, AW
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 : 501 - 503
  • [2] A 5-COORDINATE RUTHENIUM(I) COMPLEX
    BIANCHINI, C
    LASCHI, F
    PERUZZINI, M
    ZANELLO, P
    GAZZETTA CHIMICA ITALIANA, 1994, 124 (06): : 271 - 274
  • [3] Nitrosyl, nitro, and nitrato complexes of palladium(IV).: The first structurally characterized mononuclear nitrosyl complex of palladium
    Cámpora, J
    Palma, P
    del Río, D
    Carmona, E
    Graiff, C
    Tiripicchio, A
    ORGANOMETALLICS, 2003, 22 (17) : 3345 - 3347
  • [4] 5-COORDINATE COMPLEXES OF PLATINUM(2) AND PALLADIUM(2)
    FACKLER, JP
    SEIDEL, WC
    FETCHIN, JA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (10) : 2707 - &
  • [5] The first example of a structurally characterized octahedral hydrotris(pyrazolyl)borate iron methyl complex
    Graziani, O
    Toupet, L
    Hamon, JR
    Tilset, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 669 (1-2) : 200 - 206
  • [6] The first example of a structurally characterized monomeric bismuth selenolate
    Mugesh, G
    Singh, HB
    Butcher, RJ
    JOURNAL OF CHEMICAL RESEARCH-S, 1999, (07): : 416 - U17
  • [7] A 5-COORDINATE PT(II) COMPLEX OF PYRIDYLMETHYLAMINEDIACETATE
    WINTER, JA
    LIN, FTA
    SHEPHERD, RE
    INORGANICA CHIMICA ACTA, 1989, 155 (02) : 155 - 159
  • [8] SYNTHESIS AND STRUCTURE OF A 5-COORDINATE TRIARYLGALLIUM COMPLEX
    COGGIN, DK
    FANWICK, PE
    GREEN, MA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 288 - INOR
  • [9] UNUSUAL 5-COORDINATE COMPLEX OF COPPER(II)
    LOTT, AL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (20) : 5313 - &
  • [10] SYNTHESIS AND STRUCTURE OF A 5-COORDINATE TRIARYLGALLIUM COMPLEX
    COGGIN, DAK
    FANWICK, PE
    GREEN, MA
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (14) : 1127 - 1129
12345