Indium triflate - An efficient catalyst for hetero Diels-Alder reactions

被引:91
|
作者
Ali, T [1 ]
Chauhan, KK [1 ]
Frost, CG [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
关键词
indium triflate; catalysis; hetero Diels-Alder; library synthesis;
D O I
10.1016/S0040-4039(99)01045-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
At a loading as low as 0.5 mol% indium triflate has been found to catalyse the hetero Diels-Alder reaction. A three component coupling reaction between aldehydes, amines and Danishefsky's diene to afford tetrahydropyridine derivatives proceeds similarly in high yield. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:5621 / 5624
页数:4
相关论文
共 50 条
  • [1] DIIODOSAMARIUM, A CATALYST PRECURSOR FOR DIELS-ALDER AND HETERO-DIELS-ALDER REACTIONS
    VANDEWEGHE, P
    COLLIN, J
    TETRAHEDRON LETTERS, 1994, 35 (16) : 2545 - 2548
  • [2] Indium triflate-catalysed Diels-Alder reactions of isochromenylium cations with enones
    Selvi, Thangavel
    Srinivasan, Kannupal
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2013, 11 (13) : 2162 - 2167
  • [3] Indium trichloride: a useful catalyst for ionic Diels-Alder reactions
    Reddy, BG
    Kumareswaran, R
    Vankar, YD
    TETRAHEDRON LETTERS, 2000, 41 (52) : 10333 - 10336
  • [4] Regioselectivity in Hetero Diels-Alder Reactions
    Grosso, Carla
    Liber, Marta
    Brigas, Amadeu F.
    Pinho e Melo, Teresa M. V. D.
    Lemos, Americo
    JOURNAL OF CHEMICAL EDUCATION, 2019, 96 (01) : 148 - 152
  • [5] α,β-Unsaturated thioacylsilanes as efficient dienes in hetero Diels-Alder reactions
    Capperucci, A
    Degl'Innocenti, A
    Nocentini, T
    Biondi, S
    Dini, F
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 686 (1-2) : 363 - 367
  • [6] Recent Contributions to Hetero Diels-Alder Reactions
    Blond, Gaelle
    Gulea, Mihaela
    Mamane, Victor
    CURRENT ORGANIC CHEMISTRY, 2016, 20 (21) : 2161 - 2210
  • [7] Bismuth(III) triflate as catalyst in Diels-Alder carbonyl reaction
    Oussaid, A
    Garrigues, B
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2002, 177 (04) : 825 - 832
  • [8] Hetero Diels-Alder reactions of nitrosoamidines: An efficient method for the synthesis of functionalized guanidines
    Miller, CA
    Batey, RA
    ORGANIC LETTERS, 2004, 6 (05) : 699 - 702
  • [9] New findings in hetero Diels-Alder reactions of quinolinetriones
    Blanco, MD
    Alonso, MA
    Avendano, C
    Menendez, JC
    TETRAHEDRON, 1996, 52 (16) : 5933 - 5944
  • [10] Hetero Diels-Alder reactions of 3-formylchromones
    Zimmerman, Jake R.
    McCarthy, Allison M.
    Bouhall, Samantha
    Manpadi, Madhuri
    Myers, Brian J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245