Electrochemical formation and composition analysis of ZnxCd1-xSe solid solutions

被引：10
|
作者：
Bouroushian, M [1 ]
Kosanovic, T [1 ]
机构：
[1] Natl Tech Univ Athens, Sch Chem Engn, Gen Chem Lab, Athens 15780, Greece
来源：
JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 2006年 / 10卷 / 04期
关键词：
zinc-cadmium-selenide; electrodeposition; X-ray diffraction; solid solutions;
D O I：
10.1007/s10008-005-0670-x
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The direct growth of ZnSe-CdSe solid solution onto metallic cathodes by electrodeposition from acidic aqueous sulphate solutions is described. The plating process is studied by simple voltammetry, while the structure and composition of the electrolytic deposits are investigated by X-ray diffraction. The experimental d-spacing values of the as-grown mixed lattice are compared to data from reference Zn (x) Cd1-x Se pellets of standard composition, produced by a sintering method. The findings are supplemented with energy-dispersive X-ray (EDX) elemental analysis. Thereupon, the variation of the mole fraction x in Zn (x) Cd1-x Se, and the solid phase constitution of the electrodeposits are determined and correlated to the electrochemical conditions of growth. The resulting films contain admixtures of CdSe compound and metallic Cd.
引用
收藏
页码：223 / 229
页数：7
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