Density and excess molar volume in a binary mixture of o-anisaldehyde and chlorobenzene at 303.15, 313.15, and 323.15 K

被引:6
|
作者
Baskaran, R. [1 ]
Kubendran, T. R. [1 ]
机构
[1] Anna Univ, AC Coll Technol, Dept Chem Engn, Madras 25, Tamil Nadu, India
关键词
Chlorobenzene; Excess Volume; Excess Molar Volume; Entire Composition Range; Binary Liquid Mixture;
D O I
10.1134/S0036024409030054
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The properties associated with the liquids and liquid mixtures like density, and excess molar volume find extensive application in chemical engineering design. These properties are important from practical and theoretical point of view to understand liquid theory and provide information about molecular interactions. The objective of the present paper is to determine density (rho) of a binary liquid mixture of o-anisaldehyde and chlorobenzene over the entire composition range at 303.15, 313.15, and 323.15 K. Excess molar volume (V (E)) from the ideal behavior over the entire mole fraction range was calculated. Excess molar volume was fitted to Redlich-Kister type equation. It was found that in all cases, the experimental data obtained fitted with the values correlated by the model very well. The molecular interactions existing between the components were discussed.
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页码:350 / 352
页数:3
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