A new exact method for solving the two-dimensional Ising model

被引:14
|
作者
Ranjbar, S
Parsafar, GA [1 ]
机构
[1] Isfahan Univ Technol, Dept Chem, Esfahan 85154, Iran
[2] Razi Univ, Coll Sci, Dept Chem, Kermanshah, Iran
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 1999年 / 103卷 / 35期
关键词
D O I
10.1021/jp9902203
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have used the two-dimensional Ising model with a limited number of rows, but with the coordination number of four for each site, to set up the transfer matrix for the model. From the solution of such a matrix, the exact thermodynamic properties have been obtained for the model with a definite number of rows, n. We have solved the matrix for n less than or equal to 7 and n less than or equal to 10 in the presence and absence of a magnetic field, respectively. On the basis of such solutions, we have proposed an analytical expression for the partition function of the model with any number of rows in the absence of a magnetic field. The proposed expression becomes more accurate when n is larger, in such a way that it becomes very accurate for n greater than or equal to 8 and is exact for n -->infinity. Our results show that the singularity of the specific heat occurs only for the model with infinite number of rows. In the presence of a magnetic field, the solution to the matrixes is too complicated to propose a general analytical expression for the partition function of the model with any number of rows. However, our exact solution for the model with n = 4, 5, 6, and 7 reveals an important point that such results are independent of n when the field-spin interaction energy is almost equal to or larger than that of the spin-spin interaction.
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页码:7514 / 7521
页数:8
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