Ionic-liquid-assisted synthesis of the phosphorus interhalides [PBr4][IBr2] and [PBr4][I5Br7]

被引：12

作者：

Hausmann, David ^{[1
]}

Koppe, Ralf ^{[1
]}

Wolf, Silke ^{[1
]}

Roesky, Peter W. ^{[1
]}

Feldmann, Claus ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Anorgan Chem, Engesserstr 15, D-76131 Karlsruhe, Germany

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 41期

关键词：

SENSITIZED SOLAR-CELLS; CRYSTAL-STRUCTURE; RAMAN-SPECTRA; IODINE; SALTS; MONOANIONS; BROMINE; ANIONS; POLYHALIDES; HALOGEN;

D O I：

10.1039/c6dt03303b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The phosphorus interhalides [PBr4][IBr2] (1) and [PBr4](2)[I5Br7] (2) were prepared by reaction of PBr5 and the interhalogen IBr in the ionic liquid [MeBu3N][N(Tf)(2)] (N(Tf)(2): bis(trifluoromethylsulfonyl)amide). [PBr4][IBr2] (1) consists of tetrahedral [PBr4](+) cations and linear [IBr2](-) anions. [PBr4](2)[I5Br7] (2) also contains [PBr4](+) cations as well as the iodine bromide anion [I5Br7](2-). The latter represents the yet largest known polyiodinebromide. Moreover, (2) shows remarkable halogen release (IBr and Br-2) of 96.8 wt% below 300 degrees C. For the ternary system P-Br-I, (1) and (2) are the first compounds that were characterized by crystal structure analysis. Composition, bonding situation and properties were further validated by energy dispersive X-ray (EDX) analysis, thermogravimetry (TG) and Raman spectroscopy.

引用

页码：16526 / 16532

页数：7

共 27 条

[1] Ionic-liquid-assisted synthesis of the phosphorus interhalides [PBr4][IBr2] and [PBr4][I5Br7] (vol 45, pg 16526, 2016)
Hausmann, David
Koeppe, Ralf
Wolf, Silke
Roesky, Peter W.
Feldmann, Claus
DALTON TRANSACTIONS, 2017, 46 (16) : 5457 - 5457
[2] RE2O7/SIO2.AL2O3-SNR4 OR -PBR4, A HIGHLY-ACTIVE CATALYST FOR THE METATHESIS OF FUNCTIONALIZED ALKENES
XU, XD
MOL, JC
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (10) : 631 - 633
[3] Ionic-Liquid-Assisted Synthesis of Nanostructured and Carbon-Coated Li3V2(PO4)3 for High-Power Electrochemical Storage Devices
Zhang, Xiaofei
Boeckenfeld, Nils
Berkemeier, Frank
Balducci, Andrea
CHEMSUSCHEM, 2014, 7 (06) : 1710 - 1718
[4] Synthesis of PbCrO4 and Pb2CrO5 rods via a microwave-assisted ionic liquid method
Wang, WW
Zhu, YJ
CRYSTAL GROWTH & DESIGN, 2005, 5 (02) : 505 - 507
[5] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF 2 NOVEL HETERONUCLEAR CLUSTER COMPOUNDS, [NET4]4[WS4CU5BR7] AND [WS4CU6I4(PY)4]N
LANG, JP
ZHOU, WY
XIN, XQ
CAI, JH
KANG, BS
YU, KB
POLYHEDRON, 1993, 12 (13) : 1647 - 1653
[6] [(Ph)3PBr][Br7], [(Bz)(Ph)3P]2[Br8], [(n-Bu)3MeN]2[Br20], [C4MPyr]2[Br20], and [(Ph)3PCl]2[Cl2l14]: Extending the Horizon of Polyhalides via Synthesis in Ionic Liquids
Wolff, Michael
Okrut, Alexander
Feldmann, Claus
INORGANIC CHEMISTRY, 2011, 50 (22) : 11683 - 11694
[7] Ionic-Liquid-Assisted Synthesis of N, F, and B Co-Doped CoFe2O4-x on Multiwalled Carbon Nanotubes with Enriched Oxygen Vacancies for Li-S Batteries
Hu, Shunyou
Yi, Mingjie
Wu, Hao
Wang, Tiansheng
Ma, Xing
Liu, Xiangli
Zhang, Jiaheng
ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (14)
[8] Synthesis of 2-amino-4-aryl-7,7-dimethyl-5-oxo-4H-5,6,7,8-tetrahydrobenzo[b]pyran derivatives in ionic liquid medium
Li, Yuling
Du, Baixiang
Wang, Xiangshan
Shi, Daqing
Tu, Shujiang
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2006, 43 (03) : 685 - 688
[9] 7-Deazapurines:Synthesis of new pyrrolo[2,3d]pyrimidin-4-onescatalyzed by a Brφnsted-acidic ionic liquid as a green and reusable catalyst
A.Davoodnia
M.Bakavoli
R.Moloudi
M.Khashi
N.Tavakoli-Hoseini
Chinese Chemical Letters, 2010, 21 (01) : 1 - 4
[10] Microwave-assisted liquid-phase synthesis of methyl 6-amino-5-cyano-4-aryl-2-methyl-4H-pyran-3-carboxylate using functional ionic liquid as soluble support
Yi, FP
Peng, YQ
Song, GH
TETRAHEDRON LETTERS, 2005, 46 (22) : 3931 - 3933

← 1 2 3 →