Study towards diversity oriented synthesis of optically active substituted cyclopentane fused carbocyclic and oxacyclic medium-sized rings: Competition between Grubbs-II catalyzed ring closing olefin metathesis and ring closing carbonyl-olefin metathesis

被引：7

作者：

Chakraborty, P. ^{[1
]}

Roy, S. C. ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, India

来源：

JOURNAL OF CHEMICAL SCIENCES | 2016年 / 128卷 / 12期

关键词：

Diversity-oriented synthesis; bicyclic frameworks; ring closing metathesis; Grubbs-II catalyst; carbonyl-olefin metathesis; ORGANIC-SYNTHESIS; NATURAL-PRODUCTS; SMALL MOLECULES; ENANTIOSELECTIVE SYNTHESIS; SKELETAL DIVERSITY; ELISABETHIN-A; SCAFFOLDS; ACID; THAPSIGARGINS; CONSTRUCTION;

D O I：

10.1007/s12039-016-1197-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study towards diversity-oriented synthesis of optically active cyclopentane fused bicyclic frameworks has been accomplished. The common intermediate was prepared from commercially available starting material (S)-carvone. The observations on competition between Grubbs-II catalyzed ring closing metathesis (RCM) and ring closing carbonyl-olefin metathesis (RCCOM) were the key features of the study.

引用

页码：1831 / 1840

页数：10

共 5 条

[1] Study towards diversity oriented synthesis of optically active substituted cyclopentane fused carbocyclic and oxacyclic medium-sized rings: Competition between Grubbs-II catalyzed ring closing olefin metathesis and ring closing carbonyl-olefin metathesis
P CHAKRABORTY
S C ROY
Journal of Chemical Sciences, 2016, 128 : 1831 - 1840
[2] Synthesis of optically active medium-sized α-aminolactams via ring-closing metathesis
Fuhshuku, Ken-ichi
Asano, Yasuhisa
TETRAHEDRON, 2012, 68 (33) : 6651 - 6655
[3] Synthesis of 2H-Chromenes via Hydrazine-Catalyzed Ring-Closing Carbonyl-Olefin Metathesis
Zhang, Yunfei
Jermaks, Janis
MacMillan, Samantha N.
Lambert, Tristan H.
ACS CATALYSIS, 2019, 9 (10): : 9259 - 9264
[4] Synthesis of 1,2-Dihydroquinolines via Hydrazine-Catalyzed Ring-Closing Carbonyl-Olefin Metathesis
Zhang, Yunfei
Sim, Jae Hun
MacMillan, Samantha N.
Lambert, Tristan H.
ORGANIC LETTERS, 2020, 22 (15) : 6026 - 6030
[5] Sequential ring-closing metathesis/Pd-catalyzed, Si-assisted cross-coupling reactions:: general synthesis of highly substituted unsaturated alcohols and medium-sized rings containing a 1,3-cis-cis diene unit
Denmark, SE
Yang, SM
TETRAHEDRON, 2004, 60 (43) : 9695 - 9708

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