The Ionic Liquid Based Synthesis of Polyaniline-MnFe2O4-CTAB Nanocomposite: Electrical Properties

被引:7
|
作者
Shafiu, S. [1 ,2 ]
Uenal, B. [3 ,4 ]
Baykal, A. [2 ,4 ]
机构
[1] Kano Univ Sci & Technol, Wudil, Kano State, Nigeria
[2] Fatih Univ, Dept Chem, TR-34500 B Cekmece Istanbul, Turkey
[3] Kano Univ Sci & Technol, Dept Elect & Elect Engn, Wudil, Kano State, Nigeria
[4] Kano Univ Sci & Technol, Dept BioNano Technol, R&D Ctr, Wudil, Kano State, Nigeria
关键词
Ionic liquid; Conductivity; Dielectric properties; Nanocomposite; MAGNETIC-PROPERTIES; POLYANILINE; NANORODS;
D O I
10.1007/s10904-013-9928-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polyaniline (PANI)-MnFe2O4 nanocomposite was successfully synthesized by using 1-butyl-3-methyl-imidazolium bromide as ionic liquid and cetyl trimethylammonium bromide as surfactant via in situ polymerization. Structural, morphological, spectral and magnetic investigation of the product were done by X-ray powder diffractometry, fourier transform infrared spectroscopy, thermal gravimetric analyzer, transmission electron microscopy, vibrating sample magnetometry respectively. Electrical properties of PANI-MnFe2O4-CTAB nanocomposite was characterized with a measurement of an impedance spectroscopy, which was evaluated at frequency range varying from 1 Hz to 3 MHz for temperature range of 20-120 A degrees C. In general ac conductivity remained almost unchanged until it reaches up to 160 kHz, and then reduced slightly almost for all temperatures except for some slight fluctuation somehow.
引用
收藏
页码:1335 / 1340
页数:6
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