Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d6-metal alkynyl complexes

被引：23
|
作者：
Drouet, Samuel [2 ]
Merhi, Areej [3 ]
Grelaud, Guillaume [1 ,2 ]
Cifuentes, Marie P. [1 ]
Humphrey, Mark G. [1 ]
Matczyszyn, Katarzyna [4 ]
Samoc, Marek [4 ,5 ]
Toupet, Loic [6 ]
Paul-Roth, Christine O. [2 ,3 ]
Paul, Frederic [2 ]
机构：
[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
[2] Univ Rennes 1, UMR CNRS 6226, Inst Sci Chim Rennes, F-35042 Rennes, France
[3] Univ Europeenne Bretagne, INSA Rennes, INSA ISCR UMR 6226, F-35043 Rennes, France
[4] Wroclaw Univ Technol, Inst Phys & Theoret Chem, PL-50370 Wroclaw, Poland
[5] Australian Natl Univ, Laser Phys Ctr, Canberra, ACT 0200, Australia
[6] Univ Rennes 1, UMR CNRS 6251, IPR, F-35042 Rennes, France
来源：
NEW JOURNAL OF CHEMISTRY | 2012年 / 36卷 / 11期
基金：
澳大利亚研究理事会;
关键词：
NONLINEAR-OPTICAL PROPERTIES; CONJUGATED PORPHYRIN DIMERS; IRON SIGMA-ACETYLIDES; STATES; MODEL; NMR;
D O I：
10.1039/c2nj40589j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The syntheses of new Zn(II) tetraphenylporphyrin (ZnTPP) derivatives functionalized with electron-rich d(6)-transition metal alkynyl complexes at their periphery are reported. Z-scan measurements reveal remarkably large effective two-photon absorption (TPA) cross-sections in the visible range for these compounds.
引用
收藏
页码：2192 / 2195
页数：4
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