Synthesis of Fused Pyran Derivatives via Visible-Light-Induced Cascade Cyclization of 1,7-Enynes with Acyl Chlorides

被引：110

作者：

Li, Chen-Guang ^{[1
]}

Xu, Guo-Qjang ^{[1
]}

Xu, Peng-Fei ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China

来源：

ORGANIC LETTERS | 2017年 / 19卷 / 03期

关键词：

DIASTEREOSELECTIVE SYNTHESIS; DECARBOXYLATIVE ARYLATION; N-ARYLACRYLAMIDES; CARBOXYLIC-ACIDS; PHOTOREDOX; FUNCTIONALIZATION; ANNULATION; ACYLARYLATION; CONSTRUCTION; AZAPHILONES;

D O I：

10.1021/acs.orglett.6b03684

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A photocatalytic cascade cyclization of 1,7-enynes with acyl chlorides has been established. This method offers an operationally simple access to diverse fused pyran derivatives with a broad substrate scope in high yields from simple acyl chlorides via an acyl radical intermediate.

引用

页码：512 / 515

页数：4

共 50 条

[1] Visible-Light-Induced Trifluoromethylation/Cyclization of 1,7-Enynes in Continuous Flow
Zhuang, Kaiqiang
Cui, Yusheng
Yuan, Xin
Qin, Longzhou
Sun, Qi
Duan, Xiu
Chen, Lin
Zhang, Xinpeng
Qiu, Jiangkai
Guo, Kai
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (31): : 11729 - 11736
[2] Visible-light-induced alkoxycarbonylation/cyclization of 1,7-enynes: synthesis of dihydropyranones containing all-carbon quaternary centers
Chen, Jian-Qiang
Chen, Qi
Chen, Baofu
Wu, Jie
ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (08) : 2018 - 2023
[3] Recent Advances in the Cascade Cyclization Reactions of 1,7-Enynes
Zhang, Xue-Song
Han, Ya-Ping
Liang, Yong-Min
ADVANCED SYNTHESIS & CATALYSIS, 2024, 366 (03) : 324 - 356
[4] Synthesis of Benzoazepinone Derivatives via Photoredox Deaminative Radical Cascade Alkylation of 1,7-Dienes and 1,7-Enynes
de Souza, Wanderson C. C.
Lima, Rafaely N. N.
de Jesus, Iva S. S.
Correia, Jose Tiago M.
Paixao, Marcio W.
SYNTHESIS-STUTTGART, 2022, 55 (06): : 967 - 976
[5] Formation of cyclopenta[c]quinolines through visible-light-induced photoredox cascade bis-annulations of 1,7-enynes with sulfoxonium ylides
Xian, Ning
Deng, Guo-Jun
Huang, Huawen
ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, 22 (37) : 7618 - 7622
[6] Visible-light-induced cascade radical cyclization for the synthesis of amide-functionalized fused quinazolinones
Gao, Shenyuan
Xu, Gang
Yang, Jianhai
Lin, Peng
Jiang, Dapeng
Wang, Xiaozhong
Cai, Menglu
Dai, Liyan
TETRAHEDRON, 2024, 159
[7] Visible-light-induced radical cascade sulfonylation/cyclization towards indole-fused pyridine derivatives
Du, Qin
Pan, Ruohan
Chen, Yu
Tang, Yucai
RSC ADVANCES, 2025, 15 (01) : 216 - 222
[8] Visible-Light-Induced Tandem Cyclization of 1,7-Enynes to Access Phenanthridin-6(5H)-Ones Using a Polydimethylsiloxane (PDMS) Based Microreactor
Ravi, Dharavath
Prasad, Vadla Shiva
Rao, Vadithya Ranga
Krishna, Silari Mohana
Kumar, Chelukalapally Anil
Saha, Biswajit
Adiyala, Praveen Reddy
CHEMPHOTOCHEM, 2025,
[9] A Facile Synthesis of Functionalized Benzofurans via Visible-Light-Induced Tandem Cyclization of 1,6-Enynes with Disulfides
Li, Xuezhi
Xu, Zhaoliang
Wang, Lei
Wang, Fang
Yang, Jianguo
Li, Pinhua
CHEMPHOTOCHEM, 2021, 5 (02): : 142 - 148
[10] Synthesis of indolo[2,1-a]isoquinoline derivatives via visible-light-induced radical cascade cyclization reactions
Wei, Yun-Long
Chen, Jian-Qiang
Sun, Bo
Xu, Peng-Fei
CHEMICAL COMMUNICATIONS, 2019, 55 (42) : 5922 - 5925

← 1 2 3 4 5 →