Bis cinnamate substituted λ-shaped azo liquid crystal: effect of molecular structure on mesomorphic properties

被引：1

作者：

Shukla, Devendra K. ^{[1
]}

Sharma, Vinay S. ^{[2
,3
]}

Sharma, Anuj S. ^{[1
]}

Hitendra, Mali ^{[2
]}

Shah, R. R. ^{[1
]}

机构：

[1] Gujarat Univ, KK Shah Jarodwala Maninagar Sci Coll, Dept Chem, Ahmadabad, India

[2] Gujarat Univ, Sch Sci, Dept Chem, Ahmadabad, India

[3] Gujarat Univ, Sch Sci, Dept Chem, Ahmadabad 380009, India

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2023年 / 765卷 / 01期

关键词：

Azo; cinnamate; enantiotropic; liquid crystal; nematic; smectic; TERMINAL SUBSTITUENTS; MESOPHASE BEHAVIOR; LATERAL METHYL; SIDE-CHAIN; ESTER; PHASE; ALIGNMENT; MOIETY; DYES;

D O I：

10.1080/15421406.2023.2210948

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new class of lambda-shaped azo materials with a cinnamate linkage group has been designed, synthesized, and well-characterized. Further, the liquid crystalline property has been studied by using POM and DSC analysis. Out of six derivatives, five compounds displayed liquid crystalline properties. The liquid crystalline property is observed in an enantiotropic manner. The structure-property relationship is further studied for the understanding of the exhibition of liquid crystalline properties. The results showed that their liquid crystalline phase behavior was closely related to the number of mesogenic units, rigidity, and flexibility of the molecular systems.

引用

页码：10 / 25

页数：16

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