Resolving electron and hole transport properties in semiconductor materials by constant light-induced magneto transport

被引:8
|
作者
Musiienko, Artem [1 ]
Yang, Fengjiu [1 ,2 ]
Gries, Thomas William [1 ,3 ]
Frasca, Chiara [1 ,3 ]
Friedrich, Dennis [4 ]
Al-Ashouri, Amran [1 ]
Saglamkaya, Elifnaz [5 ]
Lang, Felix [6 ]
Kojda, Danny [7 ]
Huang, Yi-Teng [8 ,9 ]
Stacchini, Valerio [1 ]
Hoye, Robert [9 ]
Ahmadi, Mahshid [10 ]
Kanak, Andrii [11 ,12 ]
Abate, Antonio [1 ,3 ]
机构
[1] Helmholtz Zentrum Berlin Mat & Energie GmbH, Solar Energy, D-12489 Berlin, Germany
[2] Natl Renewable Energy Lab, Chem & Nanosci Ctr, Golden, CO 80401 USA
[3] Univ Bielefeld, Dept Chem, Bielefeld, Germany
[4] Helmholtz Zentrum Berlin Mat & Energie GmbH, Inst Solar Fuels, D-14109 Berlin, Germany
[5] Univ Potsdam, Inst Phys & Astron, Disordered Semicond Optoelect, Karl Liebknecht Str 24-25, D-14476 Potsdam, Germany
[6] Univ Potsdam, Inst Phys & Astron, ROSI Freigeist Juniorgrp, Karl Liebknecht Str 24-25, D-14476 Potsdam, Germany
[7] Helmholtz Zentrum Berlin Mat & Energie GmbH, Dept Dynam & Transport Quantum Mat, D-14109 Berlin, Germany
[8] Univ Cambridge, Cavendish Lab, JJ Thomson Ave, Cambridge CB3 0HE, England
[9] Univ Oxford, Dept Chem, Inorgan Chem Lab, South Parks Rd, Oxford OX1 3QR, England
[10] Univ Tennessee, Inst Adv Mat & Mfg, Dept Mat Sci & Engn, Knoxville, TN 37996 USA
[11] Dept Chem & Appl Biosci, Lab Inorgan Chem, ETH Zurich, Zurich, Switzerland
[12] Yuriy Fedkovych Chernivtsi Natl Univ, Dept Gen Chem & Chem Mat, UA-58012 Chernovtsy, Ukraine
基金
英国工程与自然科学研究理事会;
关键词
SINGLE-CRYSTALS; SOLAR-CELLS; PEROVSKITE;
D O I
10.1038/s41467-023-44418-1
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The knowledge of minority and majority charge carrier properties enables controlling the performance of solar cells, transistors, detectors, sensors, and LEDs. Here, we developed the constant light induced magneto transport method which resolves electron and hole mobility, lifetime, diffusion coefficient and length, and quasi-Fermi level splitting. We demonstrate the implication of the constant light induced magneto transport for silicon and metal halide perovskite films. We resolve the transport properties of electrons and holes predicting the material's effectiveness for solar cell application without making the full device. The accessibility of fourteen material parameters paves the way for in-depth exploration of causal mechanisms limiting the efficiency and functionality of material structures. To demonstrate broad applicability, we further characterized twelve materials with drift mobilities spanning from 10-3 to 103 cm2V-1s-1 and lifetimes varying between 10-9 and 10-3 seconds. The universality of our method its potential to advance optoelectronic devices in various technological fields. Here, the authors introduce a constant light-induced magneto-transport method which seamlessly integrates light, current, and a magnetic field to characterize electron and hole properties across an expansive array of materials.
引用
收藏
页数:11
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