Age and petrogenesis of ore-forming volcanic-subvolcanic rocks in the Yidonglinchang Au deposit, Lesser Xing'an Range: Implications for late Mesozoic Au mineralization in NE China

The age and petrogenesis of volcanic-subvolcanic rocks associated with Au mineralization of the recently discovered Yidonglinchang Au deposit in the Lesser Xing'an Range provide insights into late Mesozoic Au metallogenesis in NE China. In this paper, we report zircon U-Pb chronological and Hf isotopic, whole-rock geochemical, and Sr-Nd isotopic data of the andesite porphyry and quartz diorite porphyry from the Yidonglinchang Au deposit. Zircon U-Pb dating shows that the andesite porphyry and quartz diorite porphyry associated with Au mineralization were formed at 101 and 99-97 Ma, respectively, suggestive of an early Late Cretaceous Au mineralization event in the Lesser Xing'an Range. Whole-rock geochemical data reveal that they have low SiO2 contents (59.87-61.48 % and 55.91-63.22 %, respectively) and high Mg# values (41.5-55.4 and 43.2-61.3, respectively). In addition, these rocks are enriched in large-ion lithophile elements (e.g., K, Rb, and Ba) and depleted in high-field-strength elements (e.g., Nb, Ta, P, Ti, Zr, and Hf). The rocks have slightly negative to positive zircon epsilon Hf(t) values (-2.3 to 5.7) and negative whole-rock epsilon Nd(t) values (-3.3 to -2.9), indicating a metasomatized mantle source with some contamination by crustal materials. Combined with regional magmatic and metallogenic characteristics, we conclude that the Au mineralization at Yidonglinchang formed as a result of early Late Cretaceous magmatic-hydrothermal activities. Previously obtained data show that the orogenic Au deposits in the northern NE China formed mainly during the Early Cretaceous, earlier than the late Early Cretaceous to Late Cretaceous epithermal Au deposits in the eastern NE China. The formation of the late Mesozoic Au mineralization in the northern and eastern NE China was likely controlled by distinct tectonic settings. During the late Early to early Late Cretaceous, the rollback of Paleo-Pacific oceanic slab beneath eastern NE China generated an extensional setting that led to large-scale magmatism and associated Au mineralization.