Tandem conversion xylose to 2-methylfuran with NiCu/C catalyst

被引：5

作者：

Li, Hao ^{[1
,2
]}

Liu, Huimin ^{[2
]}

Cai, Chiliu ^{[2
]}

Wang, Haiyong ^{[2
]}

Huang, Youwang ^{[3
]}

Li, Song ^{[2
]}

Yang, Bin ^{[2
]}

Wang, Chenguang ^{[2
]}

Liao, Yuhe ^{[2
]}

Ma, Longlong ^{[4
]}

机构：

[1] Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China

[2] Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China

[3] Hebei Univ Technol, Coll Chem Engn, Tianjin 300401, Peoples R China

[4] Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2023年 / 175卷

关键词：

Xylose; 2-Methylfuran; NiCu; C catalyst; Hydrogenation; Dehydration; FURFURYL ALCOHOL; SELECTIVE HYDROGENATION; BIOMASS; REDUCTION; FUELS; ACID;

D O I：

10.1016/j.catcom.2023.106625

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nowadays, 2-methylfuran is urgently needed especially in pharmaceutical manufacture. However, the direct synthesis of 2-methylfuran via the efficient dehydration and hydrogenation of xylose usually requires a multistep reaction. Herein, a route of tandem conversion xylose to 2-methylfuran was developed. The xylose was firstly converted into furfural by H beta zeolite, followed by the catalysis of furfural to 2-methylfuran over 0.5NiCu/C. Compared with two-step reaction, cascade strategy applied xylose conversion improved the 2-methylfuran yield rate by 41.5%. In general, this work expanded the application of tandem method for the enhancement of xylose effective conversion and provided a new biomass utilization technology.

引用

页数：7

共 50 条

[1] Bifunctional catalyst for conversion of 2-methylfuran to biodiesel
Wen, Cun
Lauterbach, Jochen
Hattrick-Simpers, Jason
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
[2] Conversion of Xylose to Furfuryl Alcohol and 2-Methylfuran in a Continuous Fixed-Bed Reactor
Cui, Jinglei
Tan, Jingjing
Cui, Xiaojing
Zhu, Yulei
Deng, Tiansheng
Ding, Guoqiang
Li, Yongwang
CHEMSUSCHEM, 2016, 9 (11) : 1259 - 1262
[3] One pot conversion of furfural to 2-methylfuran in the presence of PtCo bimetallic catalyst
Dohade, Manisha G.
Dhepe, Paresh L.
CLEAN TECHNOLOGIES AND ENVIRONMENTAL POLICY, 2018, 20 (04) : 703 - 713
[4] One pot conversion of furfural to 2-methylfuran in the presence of PtCo bimetallic catalyst
Manisha G. Dohade
Paresh L. Dhepe
Clean Technologies and Environmental Policy, 2018, 20 : 703 - 713
[5] Conversion of furfuryl alcohol into 2-methylfuran at room temperature using Pd/TiO2 catalyst
Iqbal, Sarwat
Liu, Xi
Aldosari, Obaid F.
Miedziak, Peter J.
Edwards, Jennifer K.
Brett, Gemma L.
Akram, Adeeba
King, Gavin M.
Davies, Thomas E.
Morgan, David J.
Knight, David K.
Hutchings, Graham J.
CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (08) : 2280 - 2286
[6] INVESTIGATION OF THE MECHANISM OF HYDROGENATION AND HYDROGENOLYSIS OF 2-METHYLFURAN ON A PALLADIUM CATALYST
YUSKOVETS, ZG
NEKRASOV, NV
KOSTYUKOVSKII, MM
SHIMANSKAYA, MV
KIPERMAN, SL
KINETICS AND CATALYSIS, 1984, 25 (06) : 1162 - 1165
[7] Thermodynamic properties of 2-methylfuran
Ilin, D. Yu
Tarazanov, S., V
Druzhinina, A., I
Dorofeeva, O., V
Lukyanova, V. A.
Pimenova, S. M.
JOURNAL OF CHEMICAL THERMODYNAMICS, 2021, 158
[8] INVESTIGATION OF THE MECHANISM OF HYDROGENATION AND HYDROGENOLYSIS OF 2-METHYLFURAN ON A PALLADIUM CATALYST.
Yuskovets, Zh.G.
Nekrasov, N.V.
Kostyukovskii, M.M.
Shimanskaya, M.V.
Kiperman, S.L.
Kinetics and Catalysis, 1984, 25 (6 pt 1) : 1162 - 1165
[9] MECHANISM OF HYDROGENATION OF 2-METHYLFURAN
SWADESH, S
SMITH, S
DUNLOP, AP
JOURNAL OF ORGANIC CHEMISTRY, 1951, 16 (03): : 476 - 479
[10] DIPOLE MOMENT OF 2-METHYLFURAN
ANDRESEN, U
DREIZLER, H
ZEITSCHRIFT FUR NATURFORSCHUNG PART A-ASTROPHYSIK PHYSIK UND PHYSIKALISCHE CHEMIE, 1970, A 25 (04): : 570 - &

← 1 2 3 4 5 →