hr Propagating and Localized Surface Plasmon Co-Enhanced Raman Scattering Based on a Waveguide Coupling Surface Plasmon Resonance Structure

被引:5
|
作者
Wang, Lehua [1 ,2 ]
Geng, Yijia [1 ]
Zhang, Shida [1 ]
Liang, Jingqiu [1 ]
Xu, Shuping [3 ]
Liu, Yu [1 ,2 ]
机构
[1] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, State Key Lab Appl Opt, Changchun 130033, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
来源
JOURNAL OF PHYSICAL CHEMISTRY C | 2023年 / 127卷 / 08期
基金
中国国家自然科学基金;
关键词
BIOSENSOR; FLUORESCENCE; FIBER;
D O I
10.1021/acs.jpcc.2c07801
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We propose a waveguide-coupled surface plasmon resonance (WCSPR) structure with MgF2 as the waveguide layer to enhance Raman scattering. The WCSPR was a five-layer resonance structure composed of prism/Ag film/MgF2 film/outer Ag film layers. The electromagnetic field was stronger with the WCSPR structure than with a traditional SPR structure. Furthermore, localized and propagating surface plasmon co -enhanced Raman scattering of 4-mercaptopyridine was observed on the WCSPR/4-Mpy/silver-nanoparticle sandwich structure. The most effective coupling of the localized and propagating surface plasmons resulted in a 60-fold enhancement in the signal intensity relative to that obtained with a conventional SPR structure. The enhancement factor of the WCSPR/4-Mpy/silver-nanoparticle configuration was 3.6 x 107.
引用
收藏
页码:4188 / 4194
页数:7
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