Pressure-driven membrane filtration technology for terminal control of organic DBPs: A review

Disinfection by-products (DBPs), a series of undesired secondary contaminants formed during the disinfection processes, deteriorate water quality, threaten human health and endanger ecological safety. Membrane-filtration technologies are commonly used in the advanced water treatment and have shown a promising performance for removing trace contaminants. In order to gain a clearer understanding of the behavior of DBPs in membrane-filtration processes, this work dedicated to: (1) comprehensively reviewed the retention efficiency of microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) for DBPs. (2) summarized the mechanisms involved size exclusion, electrostatic repulsion and adsorption in the membrane retention of DBPs. (3) In conjunction with principal component analysis, discussed the influence of various factors (such as the characteristics of membrane and DBPs, feed solution composition and operating conditions) on the removal efficiency. In general, the characteristics of the membranes (salt rejection, molecular weight cut-off, zeta potential, etc.) and DBPs (molecular size, electrical property, hydrophobicity, polarity, etc.) fundamentally determine the membrane-filtration performance on retaining DBPs, and the actual operating environmental factors (such as solute concentration, coexisting ions/NOMs, pH and transmembrane pressure) exert a positive/ negative impact on performance to some extent. Current researches indicate that NF and RO can be effective in removing DBPs, and looking forward, we recommend that multiple factors should be taken into account that optimize the existed membrane-filtration technologies, rationalize the selection of membrane products, and develop novel membrane materials targeting the removal of DBPs.