Photoredox/Nickel Dual-Catalyzed Regioselective Allylic Arylations of Allyl Trifluoroborates with Aryl Halides

被引：5
|
作者：
Lv, Peizhuo [1 ]
Wang, Ali [1 ]
Xie, Xin [1 ]
Chen, Yulong [1 ]
Liu, Yuanhong [1 ]
机构：
[1] Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth,State Key Lab Organomet, Shanghai 200032, Peoples R China
来源：
ORGANIC LETTERS | 2023年 / 25卷 / 18期
基金：
中国国家自然科学基金;
关键词：
SINGLE-ELECTRON TRANSMETALATION; REDUCTIVE ALLYLATION; CROSS-COUPLINGS; ACYL CHLORIDES; ALCOHOLS; BROMIDES; ESTERS;
D O I：
10.1021/acs.orglett.3c01147
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient photoredox/nickel dual-catalyzed coupling of allyl trifluoroborates with aryl halides has been developed, which provides an attractive route to diverse-substituted allylic benzenes. The method offers several advantages, such as high efficiency and regioselectivity, mild reaction conditions, wide substrate scope, and functional group compatibility. Mechanistic studies suggest that a pi-allyl nickel(III) intermediate generated via the addition of an allyl radical to nickel species is possibly formed as a key reaction intermediate.
引用
收藏
页码：3319 / 3324
页数：6
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