Synthesis, structures and properties of two new selenite optical materials: K2Zn3Se4O12 and K4Zn3V4Se2O19

被引：1
|
作者：
Feng, Qiuyuan [1 ]
Gao, Zhixia [1 ]
Hou, Ketian [2 ]
Wang, Jialong [2 ]
Du, Hong [1 ]
Jing, Qun [2 ]
机构：
[1] Xinjiang Normal Univ, Coll Chem & Chem Engn, Urumqi 830054, Peoples R China
[2] Xinjiang Univ, Sch Phys Sci & Technol, Urumqi 830017, Xinjiang, Peoples R China
来源：
DALTON TRANSACTIONS | 2023年 / 52卷 / 45期
基金：
中国国家自然科学基金;
关键词：
CRYSTAL-STRUCTURES; OXIDES; MO;
D O I：
10.1039/d3dt03130f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new selenites, K2Zn3Se4O12 (compound 1) and K4Zn3V4Se2O19 (compound 2), have been successfully synthesized by solid-state reactions in vacuum tubes. Compound 1 consists of a three-dimensional (3D) framework with [SeO3] triangular pyramids and [ZnO4] tetrahedra in the monoclinic space group P2(1)/c (No. 14). Compound 1 ' s cut-off edge is below 344 nm, based on its UV-Vis-NIR diffuse reflectance studies, and theoretical calculations indicate a birefringence of around 0.043 at 1064 nm. The two-dimensional layer of compound 2, in contrast, is made up of [SeO3] triangular pyramids, [ZnO4] tetrahedra, and [V4O13] tetrahedra. It crystallizes in the monoclinic space group C2/c (No. 15). Its UV-Vis-NIR diffuse reflectance studies demonstrate that the compound's cut-off edge is lower than 330 nm.
引用
收藏
页码：16920 / 16926
页数：7
相关论文
共 50 条
  • [1] K2ZN3O4 AND RB2ZN3O4 OXOZINCATES WITH FRAMEWORK STRUCTURE
    BAIER, R
    HOPPE, R
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1987, 551 (08): : 163 - 172
  • [2] Influence of the counterions on the structures of ternary Zn/Sn/Se anions:: Synthesis and properties of [Rb10(H2O)14.5][Zn4(μ4-Se)2(SnSe4)4] and [Ba5(H2O)32][Zn5Sn(μ3-Se)4(SnSe4)4]
    Ruzin, E
    Dehnen, S
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (05): : 749 - 755
  • [3] K3FeSe3 and K3Fe2Se4, two new compounds in the system K/Fe/Se
    Bronger, W
    Genin, HS
    Müller, P
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (02): : 274 - 278
  • [4] Hydrothermal synthesis, structures and optical properties of A2Zn3(SeO3)4•XH2O (A=Li, Na, K; X=2 or 0)
    Liu, Yunsheng
    Mei, Dajiang
    Xu, Jingli
    Wu, Yuandong
    JOURNAL OF SOLID STATE CHEMISTRY, 2015, 232 : 193 - 199
  • [5] STRUCTURAL ELUCIDATIONS FOR CS2PD3SE4, RB2PD3SE4 AND K2PD3SE4
    BRONGER, W
    RENNAU, R
    SCHMITZ, D
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1987, 178 (1-4): : 39 - 41
  • [6] Hydrothermal syntheses and crystal structures of three zinc succinates:: Zn(C4H4O4)-α, Zn(C4H4O4)-β and K2Zn(C4H4O4)2
    Bowden, TA
    Milton, HL
    Slawin, AMZ
    Lightfoot, P
    DALTON TRANSACTIONS, 2003, (05) : 936 - 939
  • [7] Low dimensional materials:: Syntheses, structures, and optical properties of Rb2CuTaS4, Rb2CuTaSe4, RbCu2TaSe4, K3Ag3Ta2Se8, and Rb3AgTa2Se12
    Wu, YD
    Näther, C
    Bensch, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2004, 59 (09): : 1006 - 1014
  • [8] Synthesis, structure, and properties of V2O3(XO4)2 (X = S, Se)
    Tyutyunnik, A. P.
    Krasil'nikov, V. N.
    Zubkov, V. G.
    Perelyaeva, L. A.
    Baklanova, I. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (04) : 501 - 507
  • [9] Synthesis, structure, and properties of V2O3(XO4)2 (X = S, Se)
    A. P. Tyutyunnik
    V. N. Krasil’nikov
    V. G. Zubkov
    L. A. Perelyaeva
    I. V. Baklanova
    Russian Journal of Inorganic Chemistry, 2010, 55 : 501 - 507
  • [10] K2O-V2O4-SO3 SYSTEM
    KRASILNIKOV, VN
    GLAZYRIN, MP
    IVAKIN, AA
    ZHURNAL NEORGANICHESKOI KHIMII, 1983, 28 (08): : 2111 - 2115
12345